His and her coordinated looks never looked so sleek and sexy.
The mother of six decided against a long gown and donned a formfitting Saint Laurent by Hedi Slimane for the awards show on Sunday. The brunette beauty was effortless in the formfitting blazer and slacks, which perfectly accentuated her slim figure. Jolie sported a crisp white dress shirt with an undone bow tie, a belt and patent leather pumps.
The 38-year-old wore her long locks down in smooth waves and accessorized with Tiffany jewels. Jolie opted for a smoky eye and natural peach lips.
The 12 Years a Slave star and producer was dapper in a Valentino tuxedo for the big night.
The busy couple reunited in London on Saturday after Valentine's Day. Jolie and Pitt were last snapped together earlier this month whisking their six kids through the airport in Sydney, Australia for a flight home to the U.S. after spending some time Down Under.
Jolie and their kids have been in Australia for the past few months while she directed her new film Unbroken, while Pitt has been in England filming the WW II drama Fury.
What do you think of Brangelina's coordinated tuxes? Sound off in the comments!