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Jessica Biel

Gotcha Images / Splash News

Out of her way: Jessica Biel is on a retail mission!

The dazzling 30-year-old actress was spotted—sans hubby Justin Timberlake—Tuesday in London's fine shopping district of Mayfair.

Donning a clean gray coat and oversize sunnies, the Playing for Keeps star headed straight for one of her favorite shops, Stella McCartney. 

Although she spent the afternoon without her significant other, the two are scheduled to attend the star-studded Brit Awards tonight, where JT is slated to perform.

And while everyone can't wait for yet another sexy performance by the soulful pop star, we're certainly looking forward to seeing what his gorgeous wife will wear to the fête!