The just-married pair, who tied the knot in Italy, made their post-wedding debut by saying "I do" to helping out Hurricane Sandy victims along with producer Timbaland in Far Rockaway, New York.
The couple handed out relief backpacks for three-and-a-half hours, staying until all the trucks were emptied.
Jessica still managed to look gorgeous helping out, donning dark jeans, a padded coat and black riding boots while Justin stayed warm in a tan beanie and navy jacket. Both, of course, sported their newly acquired rings.
They're back in NYC after honeymooning in Tanzania, and it's great to see them pitching in to help those less fortunate.
If you'd like to help, text REDCROSS to 90999 ($10 donation) or visit redcross.org