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Ricky Martin, Latin Grammy Awards

Lester Cohen/WireImage

It's about to get hot on the red carpet!

The 2014 Latin Grammys are tonight, and we expect to see major stars stepping out for the event. Held in Las Vegas, the ceremony will feature some of the biggest names in Latin music and include performances by Pitbull—who will take the stage with singers Carlos Santana and Chris Brown in two separate sets—Ricky Martin and Puerto Rican band Calle 13. Rocsi Diaz, Pablo Alborán and Carlos Vives are also set to attend.

Marc Anthony, who wed model Shannon de Lima in the Dominican Republic on Nov. 11, will take to the stage for the first time since becoming a married man. Anthony is also a contender for the coveted Album of the Year award.

NEWS: Marc Anthony weds model Shannon de Lima in the Dominican Republic

This year's ceremony won't go off without a slight hitch, however—it has been announced that President Barack Obama will be airing his plans to revamp the U.S. immigration system at 8 p.m. ET, when the show was set to start on the East Coast. Univision, the Spanish-language network that will air the awards, plans to delay its East Coast broadcast for Obama's speech.

The Latin Grammys air tonight at 8 p.m. ET/7 p.m. CT on Univision.

See more celebs on the star-studded 2014 Latin Grammys red carpet!

PHOTOS: The 2014 Latin Grammys red carpet arrivals