It was all about Hollywood royalty at Kensington Palace in London today.
And, not surprising, the pretty pair simply stunned in coordinating black outfits, with the 38-year-old actress wearing a custom Atelier Versace gown.
Also in attendance at the event in support of Great Ormond Street Hospital were Jolie's costars Elle Fanning and Sam Riley.
Oh, and a young gentleman by the name of Maddox Jolie-Pitt!
The couple's 12-year-old son was all smiles as he happily walked the blue carpet to meet up with his parents.
Of course, long before Pitt and Maddox entered Jolie's life, the Oscar winner envisioned a very different future for herself.
"I never thought I'd have children," the mother of six says in the June issue of Elle magazine. "I never thought I'd be in love, I never thought I'd meet the right person. Having come from a broken home—you kind of accept that certain things feel like a fairy tale, and you just don't look for them."
Meanwhile, Maleficent hit theaters later this month.