The Homeland starlet, who looked elegant in a Vionnet sheer gown and Forevermark diamonds at the SAG Awards, dished to E! News about the Dallas Buyers Club actor.
"It's great, I actually haven't seen him yet, but it will be fun," the 34-year-old actress gushed to Giuliana Rancic. "I'm very proud of him."
The duo famously portrayed on-again, off-again couple Angela Chase and Jordan Catalano on the teen drama series.
Take a look at more SAG Awards red carpet interviews you didn't see!
"It feels thrilling," Falco told Ross Mathews. "All of us who worked at those crazy jobs for all those years and wondered if you'd ever work. And here you are all these years later. You get to be with other people who say you're good enough to get this nomination, it's kind of fancy."
Who is Falco looking forward to seeing at the star-studded show? Watch the clip above to find out!
"There's a few cocktails, there's a booth involved," the Breaking Bad star revealed.
To hear what else he had to say about their outings, as well as some of the craziest fan requests, see the clip above.
30 Rock's Jane Krakowski admitted she was a bit surprised to be nominated for a SAG Award with the cast.
"We were thrilled to come and have a little surprise reunion with our gang," she told Ross on the red carpet.
Hear her dish about how she got ready for the big show!
Chiwetel Ejiofor is having an incredible awards season run, racking up the nominations and honors for his portrayal of Solomon Northup in 12 Years a Slave.
Who was the first person he spoke to after receiving his Oscar nomination? Find out now!