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    Chris Pine's Brownie Points With Piper Perabo

    Chris Pine, Piper Perabo Fotonoticias; Kevin Mazur/Getty images

    What does it take for Chris Pine to get over short-lived love Olivia Munn?

    Dinner with an equally hot femme, of course!

    Pine and Coyote Ugly sexpot Piper Perabo were spotted having drinks and sharing a brownie together for almost two hours at Napa Valley Grille in L.A.'s Westwood Village.

    "They were sitting at a four-seater table on the outdoor patio, but chose to sit right next to each other as opposed to across from each other," an eyewitness tells us. "It looked like they were peering over a script or document together."

    This wouldn't be the first script the duo has studied with one another. Pine and Perabo costarred in last year's sci-fi suspense thriller Carriers. Plus, a source tells us they may have once had a brief romance.

    Keep reading for more couples news, including what we caught Justin Timberlake and Jessica Biel doing together...

    V.I.P. VIEWING: Jessica Biel, hosting a private screening of Valentine's Day for her family on the Warner Bros. lot in L.A. Yes, Justin Timberlake was there.

    SHAPING UP: Jeremy Piven, having lunch with a mystery woman at M Cafe Melrose in L.A.

    SEA SIDE: Victoria Beckham with sons Brooklyn, Cruz and Romeo, grabbing gelato at ChocolateBox Café after spending a day on the beach in Malibu.

    ASIAN PERSUASION: Eva Mendes, eating Thai food at Nakkara on Beverly in L.A.

    SUSHI SESH: Kristin Davis, dining with an unknown fella at Katsuya restaurant in Hollywood.

    PARENTS-TO-BE: Robin Thicke and pregnant wife Paula Patton, grabbing a bite to eat at La Conversation in West Hollywood.

    LET'S GET PHYSICAL: J.C. Chasez, working out with a trainer at Equinox gym just off the Sunset Strip.

    SHORE THING: Molly Sims, meeting The Situation for the first time before she headed into the Kari Feinstein Style Lounge in Miami's Gansevoort Hotel for some Zico coconut water.

    —Additional reporting by Brett Malec and Allison McNamara

    ________

    Find out what Chris Pine's Star Trek costar Zoe Saldana is doing to help Haiti.

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