There's nothing better than receiving your entertainment news by two people who have real chemistry on (and off, in this case) set.

Bill Rancic joined his lovely wife and E! News host Giuliana Rancic on the show tonight as part of this week's daily special guests, and we've gotta say—Bill did a darn good job.

Maybe this is another career avenue he could pursue?

MORE: Check Out Derek Hough Cohosting E! News—Guess Who's Joining Giuliana Next?!

Either way, Bill seemed pretty comfortable dishing the latest deets on today's biggest headlines, along with providing some reassurance for young women who were hoping to snag a catch like Mark Zuckerberg.

"Mark Zuckerberg may be off the market, but there are still plenty of single entrepreneurs out there," he said.

And of course, the Giuliana & Bill stars answered some Twitter fan questions that included whether or not they have a baby name picked out (which reminds us, don't forget to come back to E! Online this Sunday to find out if G&B are having a boy or girl!).

Tomorrow's guest cohost will be E!'s very own Kris Jenner, followed by Pete Wentz on Friday.

Tune into E! News Monday-Friday at 7 p.m. and 11:30 p.m.

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