Talk about your promising icebreakers!

Mayim Bialik sat down (and did some cooking) with Katie Couric for next Monday's episode of Katie and Katie Couric was inevitably curious about the Big Bang Theory's dating life since her split from husband Michael Stone in 2012.

Asked if she was back out there again, an almost shocked-sounding Mayim exclaimed, "No!" 

"Well, if you do, let me know," Katie offered.

"OK!" the actress agreed. "You can come out with me." Katie noted that her daughters were about the age of Mayim's two sons when she started dating again (after her husband, Jay Monahan, passed away in 1998).

Katie, Mayim Bialik

Disney/ABC

"No, I would like you by my side," Mayim said. "That sounds great."

"I'll be your wing woman!" Katie said excitedly.

To which Mayim, pretending to be introducing herself to someone, said, "'Nice to meet you, I brought Katie Couric.'"

Well, the veteran TV personality does know what she's doing. She's currently engaged to businessman John Molner.

"I'm a good wing woman, I'm not going to lie," Katie promised.

Watch the whole sneak peek to see what Mayim has to say about her relationship with her ex!

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