Miranda Lambert, ACM Awards 2014

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It was all about the duets at the 2014 Academy of Country Music Awards.

While awards show co-host Blake Shelton and Shakira performed their single, "Medicine," Sunday night for the first time, husband and wife duo Faith Hill and Tim McGraw got nostalgic with "Meanwhile Back at Mama's."

Dierks Bentley and Sheryl Crow also hit the stage at the MGM Grand Garden Arena in Las Vegas to perform "I Hold on."

Tim McGraw and Miranda Lambert were the top nominated artists going into the show, with both up for seven awards, but only one walked away the big winner of the night.

The "Mama's Broken Heart" songstress took home three awards, including Female Vocalist of the Year and Vocal Event of the Year for "We Were Us" with Keith Urban, while McGraw took home Video of the Year for "Highway Don't Care" with Taylor Swift and Urban.

The Band Perry, ACM Awards 2014

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Meanwhile, George Strait beat out Lambert, Shelton, co-host Luke Bryan and Swift for Entertainer of the Year.

Take a look at all the big winners at the 2014 ACM Awards!

Jason Aldean, ACM Awards 2014

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2014 ACM Winners:

Entertainer of the Year: George Strait

Male Vocalist of the Year: Jason Aldean

Female Vocalist of the Year: Miranda Lambert

Vocal Group of the Year: The Band Perry

Album of the Year: Same Trailer, Different Park, Kacey Musgraves

Video of the Year: "Highway Don't Care," Tim McGraw featuring Taylor Swift and Keith Urban

Taylor Swift, ACM Awards 2014

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Vocal Event of the Year: "We Were Us," Keith Urban and Miranda Lambert

Vocal Duo of the Year: Florida Georgia Line

New Artist of the Year: Justin Moore

Song of the Year: "I Drive Your Truck",  Lee Brice

Single Record of the Year: "Mama's Broken Heart", Miranda Lambert

Crystal Milestone Award: Merle Haggard

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