Naya Rivera, Rolling Stone

Terry Richardson/Art Partner Archives/Rolling Stone

Sue Sylvester must be insanely jealous right now, because Santana Lopez looks absolutely amazing!

Actually, that's Glee star Naya Rivera—out of character!—gracing Rolling Stone's Latin Hot List 2013 flip cover, which hits stands Friday, Nov. 8. In the sexy shot, Big Sean's fiancée shows off her svelte, endlessly long legs, toned tummy and sexy cleavage while posing provocatively in a fitted black one-piece and sky-high heels.

Inside the mag, which is a tribute to late rocker Lou Reed, the 26-year-old singer-actress talks about her career as a solo pop act. "It took a long time to figure out where I wanted to go musically," she says of her nearly finished debut album. She explains how she insisted Columbia, her label of three years, release her first single "Sorry" (featuring her hubby-to-be!) this summer instead of waiting for her to finish the album. She recalls telling the label, "This is what I'm doing…Get on or get off. I think this is a summer song, and I want it on the radio by the end of the summer."

VIDEO: Aw! Naya was on Arsenio Hall's show when she was just four!

Attagirl! And now, Naya and Big Sean certainly look and sound good together, but what was it that brought them together? Twitter! "We definitely need to do like a commercial for or something like that," the rapper told E! News jokingly. "We're like social networkers."

The bride-to-be added in jokingly, "Where's my endorsement?"

They'll probably be fine without it, especially if you look at that giant engagement ring Big Sean gave his lovely lady! Jewelry expert Michael O'Connor told E! News that the sparkler looked to be close to 4 carats, estimating that such a ring retails for around $70,000.

Needless to say, we're expecting a lot from their wedding!

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