Jennifer Aniston, Justin Theroux, Angelina Jolie, Brad Pitt, Victoria Beckham, David Beckham, John Krasinski, Emily Blunt

Kevin Winter/Pascal Le Segretain/Bryan Bedder/ Stephen Lovekin/Getty Images

Who runs the world? Couples! Specifically, these 25 power couples, which include Jennifer Aniston & Justin Theroux, Brad Pitt & Angelina Jolie and Emily Blunt & John Krasinski among their elite ranks.

What separated a power couple from just any old famous duo on this, the very first E! List? Everyone on our list is, to some degree, powerful in their industry, on an upward trajectory and fascinating to watch. They've got buzz, they're in demand and they're in love (awww!). 

We have have spent endless hours brainstorming, analyzing and otherwise compiling this list, which presents the pairs in no particular order. But the Top 5 Power Couples of 2013, in ranked order, will be unveiled on Thursday—Valentine's Day—both on E! News and E! Online. 

Tune in Thursday at 7 p.m. ET / 4 p.m. PT to find out who made the top 5!

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