Penn Badgley, Blake Lively, Justin Timberlake, Jessica Biel

Jamie McCarthy/WireImage; Kevin Mazur/WireImage

Lots of hot couples news today!

Us Weekly's reporting rumors that Justin Timberlake may have cheated on Jessica Biel with Olivia Munn and also that Blake Lively and Penn Badgley have—shocker—split!

Let's dig into all the dirty deets right now...including a Tom Sturridge romance update (looks like he won't be third-wheeling on Robsten's dates for much longer):

Did Justin Hookup with Olivia Munn?

According to a very detailed Us report, Justin and Munn got frisky during a three-day romp at the Gansevoort Park Avenue in New York City at the end of September.

Justin's rep vehemently denies this, but we're hearing from sources the Timberlake-Olivia hookup "definitely happened."

Munn even took to publicly supporting her love for "friend" Justin's children's fundraiser, writing on her Twitter: "For just $1, I'll love you long time... and so will @Jtimberlake."

She then redirected her followers to her website, where Munn wouldn't pipe down about the good cause and the really good person behind it all (for more star-spangled Munn click here!).

Interesting since Monday night Justin and Jessica were unusually affectionate at Chateau. Just an FYI for those of you not in the media world: Timberlake would have known then that the Olivia story was going to break in Us Weekly today since his rep was contacted.

Jess and Justin have been on-off before, and we can't help but wonder if maybe Biel has a don't-ask, don't-tell policy. She's not an idiot—she doesn't want to let J.T. go, so we wouldn't be surprised at all if they have some arrangement.

Carey Mulligan

PER/Fame Pictures

TomStu + Carey Mulligan = ...

We're thrilled about this possible more-than-friends duo!

Tom has been spotted sneaking in and out of Mulligan's Best Western digs over the last week, and the two hit up Chateau Marmont together Monday night. Carey is good pals with her Never Let Me Go costar Andrew Garfield, and we know A.G. runs in the Tom-Robert Pattinson Brit-pack group.

Here's hoping this isn't just to get back at Shia LaBeouf who slightly burned C.M. and that Sturrigan has a shot! These two are hot, hot, hot.

Gossip Girl couple is dunzo:

Color us not surprised at all that Penn Badgley and Blake Lively's rep confirmed the duo split in mid-September (the same time their rep was telling Gossip Cop that all was good).

So about the timing of that all: Blake's Disneyland date with Ryan Gosling was in mid-October! We knew something was up when they wouldn't take pics together.

As we told you, Penn and Blake have broken up and gotten back together before and still remain good friends—they were spotted shopping together in NYC just this past week. Expect Lively to be linked to all of Hollywood's hottest studs, while Badgley flies more under the radar. Maybe with—dare we hope—his Easy A costar Emma Stone?

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