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It was all about Hollywood royalty at Kensington Palace in London today.
And, not surprising, the pretty pair simply stunned in coordinating black outfits, with the 38-year-old actress wearing a custom Atelier Versace gown.
Also in attendance at the event in support of Great Ormond Street Hospital were Jolie's costars Elle Fanning and Sam Riley.
Oh, and a young gentleman by the name of Maddox Jolie-Pitt!