If you were hoping to re-watch E!'s Live From the Red Carpet coverage—or to see some interviews that didn't make it to air—you're in luck. Hollywood's hottest stars—including nominees Leonardo DiCaprio, Julia Roberts and Chiwetel Ejifor—made sure to chat with Ryan Seacrest on the red carpet. Sandra Bullock, who looked regal in Alexander McQueen, joked about her Lorraine Schwartz diamond jewelry. "I hammered them myself. I mined them myself," the Gravity star joked. "All non-conflict."

Before DiCaprio lost the Best Actor award to Dallas Buyers Club's Matthew McConaughey, the actor talked about his controversial role in The Wolf of Wall Street and the challenges he faced getting it in theaters. "This is a part of our culture nowadays, this obsession with wealth and power. It's sort of rampant in our modern culture," the movie star said. "I really wanted to make a movie about that and about these people and their value systems. It was a six-year process to put this film up on screen."

Ejifor, meanwhile, spoke to E! News' Catt Sadler after 12 Years a Slave was named Best Picture. "It's an incredible feeling. It's an absolutely extraordinary occasion and a wonderful moment for the film," he said. The Best Actor nominee later admitted that he was still in "a bit of a haze" after the big victory.

Several couples also talked to E! News, including Channing Tatum and Jenna Dewan. Asked to identify his wife's dress designer, the Magic Mike star correctly replied, "Reem Acra! Bam! Nailed it!"

Chris Hemsworth, who is expecting twins with wife Elsa Pataky, is eager to becoming a father again—just "hopefully not in the next 20 minutes or in the next couple hours," the Australian actor joked.

Click play to watch more exclusive interviews with Michael Fassbender, Portia De Rossi and more!

PHOTOS: The Oscars, as seen through stars' social media accounts

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