In the November 2016 issue of GQ, the Bad Santa 2 star reveals that differing lifestyle choices ultimately led to their 2003 divorce.
Jolie, then in her mid-20s, was named a U.N. Goodwill Ambassador in 2001, and over the next decade, would embark on more than 40 field missions to support refugees across the globe. Thornton, on the other hand, says he was more concerned with life at home.
"I never felt good enough for her," he tells the mag, adding that it was never his style to indulge in the perks of A-list coupledom.