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Helen Mirren, Ryan Reynolds

Dominique Charriau/WireImage

Talk about the power of Helen Mirren!

Blake Lively knew Ryan Reynolds was heading to Germany in support of his new movie Woman in Gold.

What she didn't expect was to see the look in her husband's eyes when he posed next to his co-star at the 65th Berlin International Film Festival.

"Should I be concerned that my husband's never looked at me this way?..." Lively joked on Instagram while her husband smiled into Mirren's eyes. "WhereAreThoseEyesWanderingReynolds."

Don't worry, guys. It's all in good fun. After all, even the Gossip Girl alumna knows that Mirren is absolutely stunning. "HelenMirrenIStheSexiestWomanAlive," she added online. "#WomanInGold."

Blake Lively, Ryan Reynolds, Cannes

Pascal Le Segretain/Getty Images

In a recent interview, Reynolds did admit to working well with Mirren on the big screen. In fact, he called her "the greatest show on Earth."

"To spend time with her anywhere, let alone on a film set, is a ball," he told Vulture. "She's just hysterical, and has no filter in the best possible way. She's as humble as you'd hope someone in her position could possibly be, and she's one of those magnetic personalities."

He added, "Everybody who meets with her flirts with her. I don't care who you are—guy, girl, fat, skinny, tall, short, gay, straight—everybody flirts with Helen Mirren."

PHOTOS: Look back at Blake Lively's pregnancy style

But once the cameras stop rolling and Reynolds is back home, it's all about his wife and their baby daughter James.

"When that happens you fall so much more in love with your partner," he told Jimmy Fallon after welcoming a child into the home. "It's a pretty crazy experience. What blows my mind is that it's so common yet it's so profound at the same time."