- Best Female Country Vocal Performance
- "Kerosene," Miranda Lambert
- "I Still Miss Someone," Martina McBride
- "Something's Gotta Give," LeAnn Rimes
- "Jesus, Take the Wheel," Carrie Underwood
- "I Don't Feel Like Loving You Today," Gretchen Wilson
- Best Male Country Vocal Performance
- "Every Mile a Memory," Dierks Bentley
- "The Reason Why," Vince Gill
- "The Seashores of Old Mexico," George Strait
- "Would You Go with Me," Josh Turner
- "Once in a Lifetime," Keith Urban
- Best Country Performance by Duo or Group with Vocal
- "Not Ready to Make Nice," Dixie Chicks
- "Heaven's My Home," the Duhks
- "Boondocks," Little Big Town
- "What Hurts the Most," Rascal Flatts
- "Leave the Pieces," the Wreckers
- Best Country Collaboration with Vocals
- "Who Says You Can't Go Home," Bon Jovi and Jennifer Nettles
- "Tomorrow Is Forever," Solomon Burke and Dolly Parton
- "Calling Me," Kenny Rogers and Don Henley
- "Midnight Angel," Rhonda Vincent and Bobby Osborne
- "Love Will Always Win," Trisha Yearwood and Garth Brooks
- Best Country Album
- Taking the Long Way, Dixie Chicks
- Like Red on a Rose, Alan Jackson
- The Road to Here, Little Big Town
- You Don't Know Me: The Songs of Cindy Walker, Willie Nelson
- Your Man, Josh Turner
- Best Latin Rock, Alternative or Urban Album
- Lo Demás Es Plástico, Black:Guayaba
- The Underdog/El Subestimado, Tego Calderón
- Calle 13, Calle 13
- Superpop Venezuela, Los Amigos Invisibles
- Amar Es Combatir, Maná
- Best Compilation Soundtrack Album for Motion Picture, Television or Other Visual Media
- Brokeback Mountain, Various Artists
- Cars, Various Artists
- Grey's Anatomy—Volume 2, Various Artists
- Little Miss Sunshine, Various Artists
- Walk the Line, Joaquin Phoenix and Various Artists
- Best Song Written for Motion Picture, Television or Other Visual Media
- "Can't Take It In" (from The Chronicles of Narnia: The Lion, the Witch and the Wardrobe), Imogen Heap, songwriter (Imogen Heap)
- "I Need to Wake Up" (from An Inconvenient Truth), Melissa Etheridge, songwriter (Melissa Etheridge)
- "Our Town" (from Cars), Randy Newman, songwriter (James Taylor)
- "There's Nothing Like a Show on Broadway" (from The Producers), Mel Brooks, songwriter (Nathan Lane and Matthew Broderick)
- "Travelin' Thru" (from Transamerica), Dolly Parton, songwriter (Dolly Parton)
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