He's a soccer futball star and professional underwear model. She's a former Spice Girl, fashion designer and frequent cover girl. Together, they're superstar parents and quite possibly the most beautiful couple on this, or any, list.
Keep clicking to see the rest of the top 25. And check back on Valentine's Day (on E! Online and E! News at 7 p.m. ET / 4 p.m. PT) to see who made the top 5 Power Couples!