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6. Jennifer Aniston and Angelina Jolie Get Engaged
Jason Thomas/FilmMagic; Marc Piasecki/WireImage; Christopher Polk/Getty ImagesNot to each other, lest you be confused. Mr. & Mrs. Smith themselves made it official when Brad Pitt put a ring on it in April. Just a few months later, Justin Theroux popped the question to his Wanderlust costar and Brad's ex-wife, Jen.
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