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Celeb Couples: How They Met
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Angelina Jolie & Brad Pitt
Jason Merritt/Getty ImagesThe Hollywood power couple met on the set of Mr. & Mrs. Smith. Even though Pitt was married to Jennifer Aniston at the time, he was soon deep into a romance with Jolie. Years later, Brangelina is still going strong with six kids, and they recently got engaged at the request of their children. Now that's love at first sight.
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