Pucker up! Smith has the best post-Grammys-win face ever and it doesn't hurt that Rihanna is kissing his cheek!
Oh no, they didn't! The actress could not handle Amy Poehler and Tina Fey's Bill Cosby jokes during their opening of the ceremony.
While the boys looked a little stunned at Miley Cyrus dancing so provocatively in her flesh-colored latex lingerie, RiRi looked bored and befuddled.
And yet another stunned group with OMG-faces and covered mouths regarding Miley Cyrus' twerk-filled performance.
The Modern Family bombshell appeared to have rolled her eyes at Julianna Margulies' nomination during the award for Outstanding Performance by a Female Actor in a Drama Series.
LOL! The country stars looked confused during Ariana Grande's performance of "The Way."
The actress was nominated for her role in Olive Kitteridge but didn't take home an award, so maybe that's why she looked so irked during the ceremony.
The supermodel's "cry face" went viral after she was caught getting pretty emotional during hubby John Legend's acceptance speech.
Of course we must include Kanye West's infamous "Imma let you finish, but Beyoncé had one of the best videos of all time," comment and the reaction it caused during Taylor Swift's acceptance speech.
hy so sad? The Canadian rapper looked as if he was making a big effort not to watch Cyrus' NSFW performance of "Blurred Lines" with Robin Thicke.
Bad sport? The "Follow Your Arrow" singer looked perplexed while losing to Miranda Lambert for Best Female Vocalist.
The sultry singer couldn't help but giggle at Ariana Grande's dance moves during "Problem."
This priceless facial expression was the director's reaction when Jennifer Lawrence lost the Best Actress Award to Emmanuelle Riva.
Yep, that's a displeased face alright. The Lincoln actor was not amused when Kristen Wiig and Will Ferrell took the stage with a quirky skit that poked fun at one of his movies, Hope Springs.
The BFFs supported the "We Can't Stop" singer by dancing and singing aloud from their front row seats. But at one point, they did appear to be in utter shock over Miley's scene-stealing antics.
Back off with the skittles, bub. That seems to be what J.Lo's manager was thinking when Casper Smart tried to play nice with his ex.
MORE PHOTOS: Wackiest Looks Ever at the Grammy Awards