Sure, the seasoned red carpet pro prefers to drape himself in models now, but how sweet is 19-year-old Leo all dressed up for his Best Supporting Actor nom for What's Eating Gilbert Grape.
The Outlander star wore Alexander McQueen at her first time at the Globes in 2016, when she landed two nominations.
Before she became a Pretty Woman, the actress wore quite the interesting pantsuit to pick up her Best Supporting Actress award for Steel Magnolias.
Before settling into her signature style, the Friends star went for a sleek, sexy look with a peek of midriff in this black tux. She garnered a Best Actress nom for her famous TV role, but she didn't take home the Globe until a year later.
The Room star hit the red carpet in Calvin Klein before picking up her first Globe for Best Actress in a Motion Picture Drama.
After picking up his first Best Actor Globe for Big, Tom flashes an adorable smile with actress Shelley Long at his first Globes.
16 years later and it's safe to say, Angie still totally owns the goth vibe. And to think it all started when she won Best Actress for the TV movie George Wallace. We gotta say, the star's over-the-top makeup is almost more eyecatching than her dress!
Far from a "trainwreck," the Best Actress in a Motion Picture, Comedy nominee hit the red carpet in style.
Her outfit may have had a case of the blues, but the young star was all smiles for her Best Supporting Actress nom for Sense and Sensibility.
Jennifer goes for the dramatic in a ruffled black and gray Louis Vuitton gown. Her Winter's Bone role nabbed her a Best Actress nomination.
The British actress, a vision in Marchesa, had a true Cinderella moment at the ceremony.
Before her days of crazy couture, the actress keeps it simple in all black on the Globes carpet with her dad for her Best Actress nom for While You Were Sleeping.
The blonde beauty was her normal, stunning self in this all-black number at the 1999 show.
The Seinfeld star stunned in this black ensemble and went home a winner at her first ever Golden Globes.
A red-headed Mirren held her award close while donning a feather hat at her first Golden Globes in 1997.
The Mr. Robot actor (and Best Actor in a Television Series, Drama nominee) cleaned up in Christian Dior.
The comedienne opted for a short number during her first Golden Globes red carpet in 2007.
The funny gal looked stunning with platinum blonde hair and a black dress at the 2009 awards show.
The funny guy was all smiles during the 2004 show.
The Scandal star rocked her baby bump to her first time at the awards show in 2014.
The How to Get Away With Murder star opted for this beige and black number while walking the red carpet during the 2009 awards show.
The Empire actress opted for a frilly, black and brown dress at her first appearance at the Golden Globes in 2009.
The '80s were a decade for big hair and even bigger fashion, and Oprah certainly showed it with this fur and fringe fail. At least she got a Best Supporting Actress nom for The Color Purple!
Costars and cowriters, the young BFFs looked super excited to attend the Globes for their hit, Good Will Hunting. The duo shared the Best Screenplay win and Matt received a nomination for Best Actor.