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EXCLUSIVE!

Source: Chris Pine and Olivia Munn Split!

Chris Pine, Olivia Munn Fotonoticias/Getty Images; Jeffrey Mayer/Getty Images

It's over.

E! News has learned exclusively that Star Trek star Chris Pine and actress/Attack of the Show host Olivia Munn have called it quits. The couple had been dating since August.

Sources tell E! News that things went south on Saturday morning for the couple, who had just enjoyed a romantic dinner at West Hollywood restaurant Madeo on Thursday night followed by partying at club Voyeur.

So what went wrong?

A source close to the couple says that Munn "was shocked and upset" when she learned Pine had been seen out with blond actress Nathalie Walker Friday night at Hollywood's Roger Room.

A source says Pine reached out to Munn, who arrived in Sundance Friday, on the phone Saturday morning to apologize, but she wasn't having any of it.

"She wouldn't answer his calls and ended up texting him, telling him to leave her alone—forever," said the source.

When contacted late Saturday, Munn's rep declined to comment on the story.

E! News is reaching out to Pine for comment.

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