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Shania Twain Ties the Knot!

Shania Twain Denise Truscello/WireImage.com

Shania Twain is a married woman…once again. 

Shortly after announcing their engagement, the 45-year-old Canadian country-pop superstar and her Swiss business exec beau, Frédéric Thiébaud, wed Saturday in an intimate ceremony in Rincon, Puerto Rico. 

But there's an ironic twist to Twain's blissful nuptials….

RELATED: Shania Twain engagement shocker! Winds up with alleged home-wrecker's husband

The newlyweds began dating after their respective spouses left them to be with each other. 

So what went down? 

Back in 2008, Twain's hubby of 14 years, Grammy-winning producer Robert "Mutt" Lange, left her for Thiébaud's then-wife (and Twain's BFF) Marie-Anne Thiébaud. The devastated duo turned to each other for solace following the split. 

And the rest, as they say, is history. Congrats!

PHOTOS: Celebrity weddings

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