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Katherine Heigl Talks Jon Bon Jovi: "Yes, I Made Out With Him!"

Jon Bon Jovi, Katherine Heigl Ethan Miller/Getty Images; Gregg DeGuire/WireImage.com

Katherine Heigl may be married to singer Josh Kelley, but he's not the man she was talking about kissing the other night when I caught up with her at Elle's Women in Hollywood gala.

The former Grey's Anatomy starlet was gushing over locking lips with another musician!

READ: Who Isn't In New Year's Eve?

Heigl plays Jon Bon Jovi's love interest in New Year's Eve, Garry Marshall's followup to Valentine's Day.

"I play a young woman who's a caterer and she's catering the New Year's Eve party and event," she explained. "Jon plays my big, famous musician ex-fiance who comes back into town to sort of win me back."

And then Heigl beamed, "Yes, I made out with him!"

How was it?

WATCH: Which A-list actress would love to direct? Check out Marc's daily video blog to find out

"It's always so nerve-wracking," she said. "There's all the giggles and there's all the Altoid popping."

And Bon Jovi couldn't have been more of a gentleman. "He's just a gem," Heigl said. "One of the nicest guys ever."

In other New Year's Eve news, Michelle Pfeiffer and Zac Efron may or may not get it on. "We have a very unusual relationship," Pfeiffer told me. "We're sort of an odd couple.

"He only really hangs out with me in the beginning, because I bribe him with super-fabulous party tickets for New Year's Eve, but then I think he grows a little fond of me," she said.

We can see why. At 53, Pfeiffer seriously remains one of the hottest women in Hollywood.

PHOTOS: Elle Women in Hollywood 2011

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