Craig, 46, and Weisz, 44, attended the Night of Opportunity Gala at Cipriani Wall Street in New York City. The actors were honored for their dedication to The Opportunity Network, a local nonprofit that puts high-achieving, low-income students on the road to the top colleges and successful careers.
Weisz, who looked stunning in Narciso Rodriguez, held hands with her husband before heading inside.
Craig recently explained why the charity effort is so close to their hearts. "We wanted to work with an organization that benefits the youth of the city and helps them thrive," he said in a press release. "The Opportunity Network's track record of helping low-income students create a path that leads them to successful careers is truly inspiring and something that Rachel and I are honored to be a part of."
Prior to Monday's outing, the A-listers walked just two red carpets together: the 70th Annual Golden Globe Awards in January 2013 and the Girl With the Dragon Tattoo premiere in January 2012. While they have attended numerous A-list events as a couple, they often eschewed being photographed.
The actors have no children together, though Weisz has a 7-year-old son, Henry, from a previous relationship with Darren Aronofsky. Craig has a 22-year-old daughter, Ella, from a previous marriage.