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TCA Press Tour, Katie Couric

Rick Rowell/ABC

Ladies, come on down!

Katie Couric announced the guests set to appear on her new talk show, Katie, over the first three weeks, and it's a parade of very lovely ladies.

Katie's series premiere (Monday, Sept. 10) will feature new mom Jessica Simpson and nine-time Grammy-winning artist Sheryl Crow. Crow, who has written the theme song for the show ("This Day"), will talk about being diagnosed with a brain tumor for the first time.

But of course the lineup for Katie isn't all about celebrity guests. Couric is also set to conduct exclusive interviews with Aimee Copeland, survivor of a rare flesh-eating bacteria, and Amanda Knox's former boyfriend Raffaele Sollecito.

The rest of the all-star guest list includes Jennifer Lopez, Barbra Streisand, 50 Shades of Grey author E.L. James, Heidi Klum, Sofia Vergara, Chelsea Handler, Demi Lovato, Susan Sarandon and Wendy Williams.