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The Amazing Spiderman, Andrew Garfield, Emma Stone

Columbia Pictures

Spider-Man costars Andrew Garfield and Emma Stone have turned into one of Hollywood's hottest couples.

They make for quite a sizzling duo—both on screen and off!

But was it love at first sight for Garfield, 28, and Stone, 23?

It was definitely something.

The Amazing Spider-Man director Marc Webb says he "immediately" noticed the chemistry between the two during their first read.

"Andrew is a great actor, very spontaneous and always aware of his moments because he comes form a super-theatrical background," Webb tells me. "Emma comes from this improvisational comedy background…Their two styles meshed. She was so funny and he was so funny."

Stone, Webb explains, "brought something out in Andrew that's just magical."

And not just in front of the cameras. "Between takes, you could just see that they had an ease with each other," Webb said. "They were having fun, they make each other laugh. I can't even explain it."

We can: It's called love.

For the record, Garfield and Stone have never officially confirmed they're dating. Webb said when people asked him about the rumors, he "just wouldn't get into that."

You're a good man (and friend), Mr. Webb.