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Brad Pitt, Angelina Jolie

Marc Piasecki/WireImage

When in Paris, look as chic as the Parisiennes do!

That's exactly what Angelina Jolie did when she hit the premiere of her flick In the Land of Blood and Honey in a drop-dead stunning ensemble—and an equally drop-dead stunning date in partner Brad Pitt.

The actress and first-time director looked amazing when she stepped out of her comfort zone of caftans and simple silhouettes and into a white-hot Ralph & Russo single-sleeve gown adorned with a dramatic grey rosette over one shoulder.

Angelina finished off the über-glamorous look with her curly locks swept over one shoulder, Jimmy Choo high heels, Lorraine Schwartz heels and that famous pout covered in va-va-voom red lipstick.

Oh, and let's not forget about her best accessory, arm candy Brad, natch who doesn't look too shabby either in a Gucci suit and matching spectacles.

What do you think of Angie's chic look? Weigh in below!