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Sean Penn, Soleil Moon Frye

THONY BELIZAIRE/AFP/Getty Images; Frederick M. Brown/Getty Images

Sean Penn has another woman in his life. (No, Scarlett Johansson has nothing to worry about.)

Former Punky Brewster star Soleil Moon Frye tells us she's headed to Haiti for a four-day trip with Penn's J/P Haitian Relief Organization.

Frye says she's been thinking about travelling to the island nation for quite some time.

"Last weekend, I bumped into Sean and told him about this dream of mine and asked him who should I go to to make this happen and he said, 'Me!'" Frye said. "I told him I'd get on the plane at any time and within a week it was confirmed for me."

While there, the über-eco mother of two will focus on the work being done to bring sustainable living to the rebuilt nation. "For over a year I wanted to go and experience Haiti and meet the people," she says. "Specifically, I've always had aspirations to help the women and kids there as they rebuild their lives."