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Prince William, Prince Harry, Pippa Middleton and James Matthews Wedding

Samir Hussein/Samir Hussein/WireImage

Looking dapper, gentlemen!

As the minutes quickly tick to the start of Pippa Middleton's wedding to James Matthews, the guests are all arriving to take their seats for the highly anticipated nuptials. 

Pippa's brother-in-law, Prince William, and Prince Harry were among the famous faces spotted on the St. Mark's Church property Saturday morning. 

The royal siblings looked handsome as they donned tailored suits with colorful vests and matching pants. Check out more of the chic arrivals below: 

 

Pippa Middleton, Kate Middleton, Pippa Middleton and James Matthews Wedding

AP Photo/Kirsty Wigglesworth, Pool

The sister of the bride headed in to take her seat alongside a bevy of youngsters. 

Prince George, Princess Charlotte, Pippa Middleton and James Matthews Wedding

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The famous siblings share a precious moment before entering the church. 

Maria Borrallo, Nanny, Pippa Middleton and James Matthews Wedding

JUSTIN TALLIS/AFP/Getty Images

Prince George and Princess Charlotte's nanny arrived to the church ahead of the two tots, who are members of Pippa's bridal party. 

James Middleton, Carole Middleton, Pippa Middleton and James Matthews Wedding

Samir Hussein/Samir Hussein/WireImage

The mother of the bride and brother of the bride headed into the church arm in arm. 

Princess Eugenie, Jack Brooksbank, Pippa Middleton and James Matthews Wedding

Samir Hussein/Samir Hussein/WireImage

The princess walked in with her boyfriend Jack Brooksbank while donning a dark dress and colorful heels. 

Donna Air, Pippa Middleton and James Matthews Wedding

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The British actress, who is dating Pippa's brother James Middleton, smiled as she arrived in a cream coat and coordinating fascinator. 

Spencer Matthews, Pippa Middleton and James Matthews Wedding

Samir Hussein/Samir Hussein/WireImage

The groom's celebrity brother looked handsome in a dark suit jacket, slate pants, an orange tie and matching pocket square. 

Roger Federer, Mirka Federer, Pippa Middleton and James Matthews Wedding

AP Photo/Kirsty Wigglesworth, Pool

The married tennis players looked chic as they headed in for the wedding. 

Looking great, everyone!