The longtime pals and former bandmates posed together on the red carpet, looking gorgeous in their dresses (which happened to be of the same color palette). Rowland opted for a sequined maroon frock, while Williams went for a blush satin gown.
E! News' Erin Lim stopped to chat with Rowland a bit about how the two prepared for their night out.
"We were actually at my house together, and I was like, 'Do you want to come with me to this event tonight?' And she was like, 'Yeah!' So we got dressed and came," she dished.
We can't help but envision them rocking out to "Bootylicious" while getting ready, but Rowland said unfortunately they don't typically listen to Destiny's Child when they're together. "Michelle was actually in the kitchen with my son, getting him to learn more words. It's amazing," she dished.
As for their third DC sister, Beyoncé, who wasn't in attendance, Rowland revealed, "We just had dinner last night!" When they're together, she admitted people can't really believe it. "They often look at us sideways, like, 'Are we really seeing this?' It's really cute."
Still, despite how much time they spend together, a reunion isn't on the table just yet.
"We haven't even talked anything about that," Rowland revealed. "We've just been enjoying each other's company and love and enjoying being women."
Williams and Rowland weren't the only reunion happening at the awards. Kristen Stewart was also in attendance and seen mingling with her former Twilight co-stars Anna Kendrick, Nikki Reed and Dakota Fanning as well as director Catherine Hardwick!
Launch the gallery above to see more photos from the event.