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Jennifer Aniston

Jason Merritt/Getty Images

Being married looks good on you, Jennifer Aniston!

The newlywed made her first red carpet appearance Wednesday night since getting married to her main man Justin Theroux.

Aniston looked positively chic in an all-black Roland Mouret ensemble as she attended the Los Angeles premiere of her upcoming flick, She's Funny That Way, in theatres this Friday.

And while all eyes were on the A-lister's ring finger, it seems as though she was sporting her wedding band sans the engagement diamond bling.

E!'s Catt Sadler caught up with the star on the red carpet and what it's like to refer to The Leftovers star as her husband.

"It feels quite natural," she said smiling. Aw! Aniston also joked about her glow being actually from sweat and not from her recent tropical honeymoon, but all signs point to the latter!

Her hubby wasn't able to attend the premiere, however, as the actress dished that "he's shooting The Leftovers in Austin."

The actress' red carpet appearance comes on the heels of photographers spotting Theroux landing at LAX airport shortly after his honeymoon in Bora Bora.

Both Theroux and his wife brought along close friends including Jason Bateman and Courteney Cox for some much-deserved R&R under the island sun. The glamorous vacation also doubled as a birthday celebration for the Leftovers star who turned 44 last Monday.

After a three-year engagement, the couple was also able to say "I Do" Aug. 5 in an intimate ceremony at their Bel-Air, Calif., home. Guests included Ellen DeGeneres, Rachel McAdams, Howard Stern and many other famous friends.

A source close to the couple tells us that their similarities helped them find a common ground when living in the spotlight.

"They live similar lives. They go their own ways but then meet back again and it works very well for them," the insider told E! News. "They seem to enjoy their time apart and then spending time to back together again."

A separate source also told us that "Justin knew she was the one from the start. He was tickled to death when they first started dating. They fell deeply in love very fast."

Congratulations once again to the newlyweds!

Be sure to tune into E! News Thursday at 7 p.m. and 11 p.m. for more on Aniston's first night out on the red carpet since her wedding!