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Reba McEntire is as vibrant and sparkly as ever post-split.

The 60-year-old country star appeared on The Tonight Show Wednesday, marking her first TV appearance since she and husband Narvel Blackstock, 58, announced their breakup last week.

Sporting a sparkling black scoop neck top, black pants, matching leather, fringed jacket, big hoop earrings and a great big smile, McEntire took the stage as a duet partner for host Jimmy Fallon; the two serenaded an audience member sitting on a stool onstage, at his request.

In their "Close-Up Serenade," the two playfully invaded the man's personal space as they crooned "Just Wanna Spend This Moment."

The singer later performed solo in a glittering gray top, black pants, matching fringed boots and a blue, embellished, lightweight jacket. She sang her new single, "Until They Don't Love You," from her new 27th studio album, Love Somebody.

Reba McEntire

Douglas Gorenstein/NBC/NBCU Photo Bank via Getty Images

McEntire had made her first major post-split appearance onstage at Musikfest 2015 in Pennsylvania on Tuesday.

Reba McEntire

Lisa Lake/Getty Images

She and her husband had announced last week that they have separated after 26 years of marriage. The two share one son, while he has three children, including Kelly Clarkson's husband Brandon Blackstock, 38, from previous relationships.